Elastic properties and Vickers hardness of optically transparent glass–ceramics with fresnoite Ba2TiSi2O8 nanocrystals

Optically transparent glass–ceramics (40BaO–20TiO2–40SiO2 (mol%)) consisting of nonlinear optical fresnoite Ba2TiSi2O8 (BTS) nanocrystals (diameter: 100–200 nm) are fabricated, and their elastic properties and deformation behavior are examined as a function of the volume fraction (f) of BTS nanocrystals using cube resonance and Vickers indentation techniques. The elastic properties such as Young's modulus (E) increases linearly with increasing the volume fraction of nanocrystals, e.g., E = 84 GPa for f = 0% (glass) to E = 107 GPa for f = 54.5%. The Vickers hardness (Hv) and indentation fracture toughness (Kc) increase from 5.0 to 6.0 GPa for Hv and 0.48 to 1.05 MPa m−1/2 for Kc with increasing the volume fraction (from f = 0% to f = 54.5%), but they do not change linearly against the volume fraction of nanocrystals. It is suggested that BTS nanocrystals themselves induce a high resistance against deformation during Vickers indenter loadings.

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► Elastic properties of glass-ceramics consisting of Ba2TiSi2O8 (BTS) nanocrystals are examined.
► Young's modulus and fracture toughness increase with the volume fraction of BTS nanocrystals.
► BTS nanocrystals induce a high resistance against deformation during Vickers indenter loadings.