Synthesis, magnetic and thermoelectric properties of Rh2MO6 (M = Mo, Te, and W) with rutile-related structure

The Rh2MO6 compounds with M = Mo, W and Te were synthesized by solid state reaction. The compounds all crystallize in a rutile-type structure. These compounds would be expected to be diamagnetic insulators if the oxidation states were Rh3+ and M6+. In fact, all show relatively high electronic conductivities with Rh2TeO6 showing the highest electronic conductivity of ∼500 S/cm at room temperature. Measurable magnetic moments also indicate valence degeneracy between Rh and the M cation. The measured Seebeck coefficients are relatively low and positive indicating hole-type conduction.

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► The Rh2MO6 compounds with M = Mo, W, and Te were synthesized with rutile-related structure.
► Relatively high electronic conductivities and measurable magnetic moment indicate valence degeneracy between Rh and M cation.
► The measured Seebeck coefficients are relatively low and positive indicating hole-type conduction.