کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1489822 992313 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structure, dielectric and piezoelectric properties of NaNbO3–Ba0.6(Bi0.5K0.5)0.4TiO3 lead-free ceramics
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Structure, dielectric and piezoelectric properties of NaNbO3–Ba0.6(Bi0.5K0.5)0.4TiO3 lead-free ceramics
چکیده انگلیسی

Lead-free ceramics (1−x)NaNbO3–xBa0.6(Bi0.5K0.5)0.4TiO3 + 1 mol% MnO2 were prepared by an ordinary sintering method and their structure, dielectric and piezoelectric properties were studied. All the ceramics possess a pure perovskite structure. The ceramics have an orthorhombic symmetry at x ≤ 0.05 and transform gradually to a tetragonal structure with x increasing. A morphotropic phase boundary is formed at 0.05 < x < 0.125. A small amount of Ba0.6(Bi0.5K0.5)0.4TiO3 (x ≥ 0.025) transforms NaNbO3 from antiferroelectric to ferroelectric and strong ferroelectricity is observed in the ceramics with x = 0.05–0.175. The ferroelectric–paraelectric phase transition becomes diffusive with x increasing. High mechanical quality factor Qm values of 1211–1862 are obtained at x = 0.05–0.075. Due to the MPB and the weakened stability of ferroelectric domain induced by the decrease in the TC, the ceramics with x = 0.10–0.175 exhibit the optimum piezoelectric properties, giving d33 = 105–131pC/N and kp = 20.8–26.5%.

Figure optionsDownload as PowerPoint slideHighlights
► New (1−x)NaNbO3–xBa0.6(Bi0.5K0.5)0.4TiO3 lead-free piezoelectric materials.
► A morphotropic phase boundary of orthorhombic and tetragonal phases is formed.
► Strong ferroelectricity, good piezoelectricity and high Curie temperature.
► The extraordinarily high Qm values (1862 and 1211) are obtained in the ceramics.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Research Bulletin - Volume 48, Issue 2, February 2013, Pages 264–269
نویسندگان
, , , , , , ,