Preparation and dielectric properties of SiC nanowires self-sacrificially templated by carbonated bacterial cellulose

SiC nanowires were synthesized by the infiltration process of reactive vapor Si in Ar atmosphere at 1350–1450 °C, using carbonated bacterial cellulose (CBC) as carbon template and a reactant. Scanning electron microscopy (SEM), powder X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), and vector network analyzer were employed to characterize the samples. The diameter of the resulting β-SiC nanowires changes with calcination temperatures, specifically, 35–60 nm for 1350 °C, 40–80 nm for 1400 °C, and 30–60 nm for 1450 °C. The β-SiC nanowires obtained at 1400 °C possess the highest ɛ″ of complex permittivity.

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► A new material – CBC is introduced as a template to prepare SiC nanowires.
► SiC nanowires are synthesized by the infiltration process of reactive vapor Si.
► The highest ɛ″ of β-SiC nanowires is obtained at 1400 °C.