Effect of La2O3, CoO, Cr2O3 and MoO3 nucleating agents on crystallization behavior and magnetic properties of ferromagnetic glass–ceramic in the system Fe2O3·CaO·ZnO·SiO2

Preparation and characterization of ferromagnetic glass ceramic in the system Fe2O3·CaO·ZnO·SiO2 with different nucleating agents was studied. The effect of La2O3, CoO, Cr2O3 and MoO3 as nucleating agents was investigated. Differential thermal analysis; X-ray diffraction and transmission electron microscope were used to investigate thermal behavior, sequence of crystallization and microstructure of the samples. XRD analysis for as prepared samples revealed the crystallization of single magnetite phase. Heat treatment at 900 °C/2 h revealed the appearance of minor amounts of calcium silicate, hematite and cristobalite beside magnetite. TEM revealed crystallization of crystallite size in the range 50–100 nm. Lattice parameters, cell volume and crystallite size were stimulated from XRD data. Magnetic properties of quenched samples were measured under 20 kG.

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► Crystallization of magnetic glass ceramic with different nucleating agents.
► The effect of La2O3, CoO, Cr2O3 and MoO3 as nucleating agents was studied.
► XRD for as prepared samples revealed crystallization of pure magnetite.
► Heat treatment revealed minor calcium silicate, hematite and cristobalite.
► TEM revealed crystallization of crystallite size in the range 50–100 nm.