Study of new states in visible light active W, N co-doped TiO2 photo catalyst

The visible light efficient W, N co-doped TiO2 photo catalysts are prepared by sol–gel method. New linkages of N, W and O are formed as NTiO, NWO, TiON and WON. Electron paramagnetic resonance illustrates the presence of oxygen vacancies in W, N co-doped TiO2 acting as trapping agencies for electrons to produce active species. X-ray photoelectron spectroscopy confirms the presence of new energy states. New linkages and oxygen vacancies are proved to be the main cause for the improved photo catalytic performances. W, N co-doped TiO2 has new energy states which narrow the band gap effectively. W, N co-doped TiO2 is thermally stable and retains its anatase phase up to 900 °C. 4.5% W, N co-doped TiO2 showed superior activity for the degradation of Rhodamine B and 2,4-dichlorophenol as compared to pure titania, Degussa P-25, traditional N-doped TiO2 and pure WO3.

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► Visible light efficient W, N co-doped TiO2 photo catalysts are prepared by sol–gel.
► Oxygen vacancies are detected in the form of new linkages as NTiO, NWO, TiON and WON.
► W, N co-doped titania has new energy states which narrows the band gap effectively.
► Oxygen vacancies are proved to be the cause for high photo catalytic activity.
► W and N co-doping plays the major role to make the composite thermally stable.