Synthesis and characterization of nanocrystalline Nd3+-doped gadolinium scandium aluminum garnet powders by a gel-combustion method

Nd3+-doped gadolinium scandium aluminum garnet (Nd:GSAG) precursor was synthesized by a gel combustion method using metal nitrates and citric acid as raw materials. The structure and morphology of the precursor and the sintered powders were studied by means of X-ray diffraction (XRD), infrared spectroscopy (IR) and transmission electron microscopy (TEM). The results showed that the precursor transformed into pure GSAG polycrystalline phase at about 800 °C, and the powders sintered at 800–1000 °C were well-dispersed with average particle sizes in the range of 30–80 nm. Optical properties of Nd:GSAG nano-powders were characterized by using photoluminescence spectroscopy. The highest photoluminescence intensity was achieved for the powder sintered at 900 °C.

The graph shows the emission spectra (λex = 808 nm) of 1 at.% Nd:GSAG powders sintered at different temperatures for 3 h. Compared with the powder sintered at 900 °C, the PL intensity of the powder sintered at 1000 °C decreased significantly. The changes in the PL intensity should mainly due to the crystallinity and dispersion of the powders.Figure optionsDownload as PowerPoint slideHighlights
► We synthesized Nd:GSAG nano-powders by gel-combustion method successfully.
► We analyzed the structure and the morphology of the heat-treated products.
► We studied the optical characteristics of Nd:GSAG nano-powders.