Spectroscopic investigations and physical properties of Mn2+ doped mixed alkali zinc borate glasses

Spectroscopic investigations on Mn2+ doped 20ZnO + xLi2O + (30−x)Na2O + 50B2O3 (5 ≤ x ≤ 25) (ZLNB) glasses reveal the non-linear behavior in their physical and structural properties. FT-IR spectra of ZLNB glasses reveal diborate units in the borate network. EPR spectra exhibit characteristic resonance signals of Mn2+ ions. A well resolved six line hyperfine structure around g = 2.02 corresponds to the sites of Type II, and a weak broad shoulder around g = 2.7 followed by an unresolved intense signal at g = 4.25 corresponding to sites of Type I are observed for their respective transitions. A large value of zero-field splitting parameter (D) is observed and it behaves non-linearly, reaches a maximum at x = 15 mol% with increase in Li2O content. Δg values reveal the ionic nature of glass systems. Optical absorption spectra suggest the distorted octahedral site symmetry of Mn2+ ions in the host. Mixed alkali effect is evident in bandgap and Urbach energies.

The EPR spectra of Mn2+doped ZLNB glass systems at room temperature exhibit the broad distribution of sites characterized by different degrees of distortion from cubic symmetry, which gives rise to intense signals at g = 4.25, which remains unchanged with respect to Li2O content for large values of D, and the other weak broad shoulder around g = 2.7 corresponds to the sites of Type I. A well resolved intense signal around g = 2.02 is characterized by weakly deformed cubic sites are observed to vary non-linearly with x mol% which corresponds to the sites of Type II features as shown in figure.Figure optionsDownload as PowerPoint slideHighlights
► These studies indicates that the structural stability is strong at x = 15 mol%.
► A rare feature of EPR spectra is observed.
► The glasses are observed to be ionic in nature.
► Mixed alkali effect is observed.