کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1492468 | 992384 | 2008 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, characterization and catalytic activity of ordered macroporous silicas functionalized with organosulfur groups
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis, characterization and catalytic activity of ordered macroporous silicas functionalized with organosulfur groups Synthesis, characterization and catalytic activity of ordered macroporous silicas functionalized with organosulfur groups](/preview/png/1492468.png)
چکیده انگلیسی
Hybrid three-dimensionally ordered macroporous (3DOM) SiO2-SO3H materials with different S/Si ratio have been prepared by colloidal crystal templating method. The process involved preparation of 3DOM SiO2-SH materials by co-condensation of (3-mercaptopropyl)triethoxysilane and tetraethoxysilane via sol-gel transformation, and following oxidation of -SH group to -SO3H group by H2O2. Materials were characterized by scanning electron microscopy (SEM), Fourier transform infra-red spectrometer (FTIR), thermogravimetric analysis (TGA), and nitrogen adsorption measurement. SEM observation shows that the macropores are highly ordered with a typical “surface-templated” structure. The surface area of 3DOM SiO2-SH material is 25.1Â m2/g and SiO2-SO3H material is 18.6Â m2/g. Catalytic activity test shows that 3DOM SiO2-SO3H materials possess a high activity for the esterification of acetic acid and n-butanol, and the activity is increased with the amount of sulfur in the materials. This study provided significant results for developing new application of 3DOM materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Research Bulletin - Volume 43, Issue 5, 6 May 2008, Pages 1209-1217
Journal: Materials Research Bulletin - Volume 43, Issue 5, 6 May 2008, Pages 1209-1217
نویسندگان
Quanzhou Wu, Jufang Liao, Qiang Yin, Yuguang Li,