کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1492847 992421 2006 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Host layer buckling in the compounds formed by exfoliation and restacking of cadmium phosphorus trisulphide with adenosine monophosphate included
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Host layer buckling in the compounds formed by exfoliation and restacking of cadmium phosphorus trisulphide with adenosine monophosphate included
چکیده انگلیسی

Exfoliated single layer cadmium phosphorus trisulphide has been combined with the biological molecule adenosine monophosphate (AMP) to form the novel restacked compound LixCd0.8PS3(AMP)z(H2O)y. Composition was determined using energy dispersive X-ray spectroscopy, and the structure of these compounds was studied using X-ray diffraction on oriented films.In the 0–80% relative humidity range, for (AMP)0.5, a host plane spacing near 19.6 Å was found. Electron density calculations based on the X-ray diffraction pattern suggest a model for the arrangement of guest AMP molecules between the host layers, with an accompanying water molecule. The calculations also suggest that there is a buckling in the host layer of about ±0.6±0.6 Å.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Research Bulletin - Volume 41, Issue 3, 9 March 2006, Pages 502–514
نویسندگان
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