کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1493538 1510783 2016 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Bulk crystal growth, optical, mechanical and ferroelectric properties of new semiorganic nonlinear optical and piezoelectric Lithium nitrate monohydrate oxalate single crystal
ترجمه فارسی عنوان
رشد کریستال فشرده، خواص اپتیکی، مکانیکی و فرآیند الکتریکی کریستال منیزیم نیترات منهیدرات آکسالات لیتیوم نیترات منفی
کلمات کلیدی
رشد کریستال تک خواص نوری، دی الکتریک، پیزو الکتریکی، فایروال الکتریکی، ویژگی های مکانیکی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
چکیده انگلیسی


• Solution grown LNO crystals showed sharp violet emission peak at 438 nm.
• Wide band gap and low Urbach energy was found in UV absorption spectra.
• Low dielectric constant along with phase change transition at 33 °C was found.
• A saturated hysteresis loop and piezoelectricity (d33 & g33) was observed.
• The SHG efficiency was found to be 1.2 times that of KDP.

New semiorganic nonlinear optical single crystals of Lithium nitrate oxalate monohydrate (LNO) were grown by slow evaporation solution technique. Single crystal X-ray diffraction study indicated that LNO crystal belongs to the triclinic system with space group P1. Various functional groups present in the material were identified by FTIR and Raman analysis. UV–vis study showed the high transparency of crystals with a wide band gap 5.01 eV. Various Optical constants i.e. Urbach energy (Eu), extinction coefficient (K), refractive index, optical conductivity, electric susceptibility with real and imaginary parts of dielectric constant were calculated using the transmittance data which have applications in optoelectronic devices. A sharp emission peak was found at 438 nm in photoluminescence measurement, which revealed suitability of crystal for fabricating violet lasers. In dielectric studies, a peak has been observed at 33 °C which is due to ferroelectric to paraelectric phase transition. Piezoelectric charge coefficients (d33 = 9.2 pC/N and g33) have been calculated, which make it a suitable for piezoelectric devices applications. In ferroelectric studies, a saturated loop was found in which the values of coercive field and remnant polarization were found to be 2.18 kV/cm and 0.39 μC/cm2, respectively. Thermal behavior was studied by TGA and DSC studies. The relative SHG efficiency of LNO was found to be 1.2 times that of KDP crystal. In microhardness study, Meyer’s index value was found to be 1.78 which revealed its soft nature. These optical, dielectric, piezoelectric, ferroelectric, mechanical and non-linear optical properties of grown crystal establish the usefulness of this material for optoelectronics, non-volatile memory and piezoelectric devices applications.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Optical Materials - Volume 51, January 2016, Pages 139–147
نویسندگان
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