Sn2SiS4, synthesis, structure, optical and electronic properties

• Sn2SiS4 has been synthesized for the first time.
• The SnS6 and SiS4 polyhedra are connected to generate a three-dimensional framework.
• Sn2SiS4 has an indirect band gap of 2.00 eV.
• Sn2SiS4 exhibits a high visible-light-induced photocatalytic reactivity.

The new ternary sulfide Sn2SiS4 has been synthesized via high-temperature solid state reaction. It crystallizes in the centrosymmetric space group P21/c of the monoclinic system. In the structure, the Sn2+ cations are coordinated to a heavily-distorted octahedron of six S atoms or a pentagonal pyramid of six S atoms, both geometries clearly demonstrating the effect of the stereo-chemically active electron lone pair on the Sn coordination environment. These SnS6 polyhedra and the SiS4 tetrahedra are connected to each other via corner and edge-sharing to generate a three-dimensional framework. Based on the diffuse reflectance measurement and the electronic structure calculation, Sn2SiS4 has an indirect band gap of 2.00 eV. Interestingly, Sn2SiS4 exhibits an efficient visible-light-driven photocatalytic activity pertaining to Rhodamine B (RhB) degradation, which is superior to the important photocatalyst C3N4. Moreover, the photocatalytic mechanism was also elucidated based on the active species trapping experiments.

Sn2SiS4 contains a three-dimensional framework built by the SnS6 and SiS4 polyhedra and exhibits interesting photocatalytic property.Figure optionsDownload high-quality image (174 K)Download as PowerPoint slide