کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1493977 1510792 2015 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of novel fluorescence xanthene–aminoquinoline conjugates, determination of dipole moment and selective fluorescence chemosensor for Th4+ ions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Synthesis of novel fluorescence xanthene–aminoquinoline conjugates, determination of dipole moment and selective fluorescence chemosensor for Th4+ ions
چکیده انگلیسی


• We designed a first based fluorescence chemosensor for Th4+ ions.
• It act as a selective fluorescence chemosensor with detection limit of 87 μM.
• The excited state and ground state dipole moment is estimated from various methods.
• Excited state dipole moment was found in the range of 9.882–1.996 D.

A series of xanthene–aminoquinoline conjugates were synthesized by following a two step procedure. All new compounds were characterized by spectral data and single crystal X-ray crystallography. Xanthene–aminoquinoline conjugates showed strong fluorescence in solution. The effect of solvent polarity, ground and excited state dipole moments of compound 2a were investigated. The ground state dipole moment was estimated to be 0.262 D, while excited state dipole moment was found in the range of 9.882–1.996 D. The effect of common metal ions on fluorescence spectra of compound 2a was also investigated. Compound 2a acts as a fluorescence chemosensor for selective detection of Th4+ ions in solution with linear range of 1 × 10−7 M to 1 × 10−5 M and detection limit of 87 μM.

Figure optionsDownload high-quality image (126 K)Download as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Optical Materials - Volume 42, April 2015, Pages 449–457
نویسندگان
, , ,