Comparative crystal field analysis of energy level schemes and nephelauxetic effect for Cr4+, Cr3+, and Mn4+ ions in Y2Sn2O7 pyrochlore

The electronic energy levels of the six-coordinated Cr4+, Cr3+, and Mn4+ ions in the pyrochlore, Y2Sn2O7, were calculated using the exchange charge model of crystal field theory. For these transition metal ions, the calculated energy levels and their trigonal splitting are in good agreement with experimental data. The calculations of the crystal field parameters show that the increased crystal field strength is related to the increased values of the moments of the 3d electron density in the sequence Mn4+ → Cr4+ → Cr3+. The nephelauxetic effect (degree of covalency) in Y2Sn2O7 was deduced by comparing the energies of the first spin-forbidden transitions of the free Cr4+, Cr3+, and Mn4+ ions with the experimentally determined values and with the estimation of the Racah parameter ratio in the crystal and in the free state. It was observed that the covalency increases in the sequence Mn4+ → Cr4+ → Cr3+, which is not easy to understand.

Nephelauxetic ratio B/B0 (left Y-axis) and red-shift of the first spin-forbidden transitions in Y2Sn2O7 with respect to free state of the Cr3+, Mn4+, and Cr4+ ions (right Y-axis).Figure optionsDownload high-quality image (96 K)Download as PowerPoint slideHighlights
► Properties of Cr4+, Cr3+, Mn4+ in Y2Sn2O7 are compared.
► Crystal field effects are compared and analyzed.
► Nephelauxetic effect is considered for all impurities.
► Relation between spin-forbidden transitions and covalency is suggested.