Prompt and delayed recombination mechanisms in Lu4Hf3O12 nanophosphors

We study lutetium hafnate, Lu4Hf3O12, prepared by acetate and citrate combustion in the form of nanometric powders. Optical properties including X-ray excited luminescence, steady-state and time resolved photoluminescence as well as thermally stimulated luminescence are investigated for undoped as well as Eu3+ and Tb3+ doped samples. We identify recombination centers in the host matrix and we tentatively associate the principal emission with a radiative transition of the F+ center. We also demonstrate that athermal tunneling of charge carriers between traps and recombination centers is the predominant mechanism of delayed radiative recombination following irradiation by ionizing radiation.

► Lutetium hafnates nanophosphors prepared by acetate and citrate combustion.
► Principal emission in the host matrix associated with the emission of the F+ center.
► Emission of the rare-earth doped material dominated by the emission of rare-earth dopants.
► Delayed radiative recombination dominated by athermal tunneling of holes.