کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1504523 | 1510998 | 2013 | 5 صفحه PDF | دانلود رایگان |
• 5–45 wt.% HPW/MCM-41 mesoporous materials were prepared and characterized.
• Their catalytic activities for benzaldehyde oxidation with H2O2 were studied.
• HPW/MCM-41 was approved to be an efficient catalyst.
• 30 wt.% HPW/MCM-41 was the optimized catalyst under the conditions.
Mesoporous molecular sieves MCM-41 and bulk 12-tungstophosphoric acid (HPW) were synthesized and employed to prepare 5–45 wt.% HPW/MCM-41 mesoporous materials. Characterization results suggested the good dispersion of HPW within MCM-41 when the loading of HPW was less than 35 wt.% and HPW/MCM-41 retained the typical mesopore structure of the supports. The results of the catalytic oxidation of benzaldehyde to benzoic acid with 30% H2O2, in the absence of any organic solvent and co-catalysts, indicated that HPW/MCM-41 was an efficient catalyst and 30 wt.% HPW/MCM-41 sample exhibited the highest catalytic activity among these materials.
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Journal: Solid State Sciences - Volume 24, October 2013, Pages 21–25