A new approach for preparation of magnetite–graphite composite: Intercalation of polyhydroxy iron cation into graphite oxide in l-arginine medium

A new approach to prepare magnetite nanoparticle pillared graphite has been put forward. The magnetic composite was normally obtained by calcining iron-intercalated graphite oxide, but the latter was prepared via intercalation reaction using polyhydroxy iron cation as iron precursor and pillaring agent, and a strong organic guanidine base, l-arginine, as alkaline agent and also intercalating agent. l-arginine, used herein instead of inorganic alkali, which would lead to the deoxygenation and reduction of graphite oxide into graphite, not only provided the alkaline condition for the formation of polyhydroxy iron cations, but also increased the interlayer spacing of graphite oxide to facilitate the intercalation of polyhydroxy iron cations into graphite oxide. The characterization by powder X-ray diffraction, transmission electron microscopy, vibrating sample magnetometer and nitrogen absorption indicated that the composite was nanoscale Fe3O4 pillared graphite with superparamagnetic property.

The magnetic composite was normally obtained by calcining iron-intercalated graphite oxide, but the latter was prepared via intercalation reaction using polyhydroxy iron cation (PIC) as iron precursor and pillaring agent, and a strong organic guanidine base, l-arginine (l-Arg), as alkaline agent and also intercalating agent.Figure optionsDownload as PowerPoint slideHighlights
► Polyhydroxy Fe replaced organic–iron complexes as Fe precursor & pillaring agent.
► An organic guanidine, l-arginine, was used as alkaline agent & intercalating agent.
► A new approach to prepare the magnetite-pillared graphite.