کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1506169 993783 2010 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Reactivity of Mg–Al hydrotalcites in solid and delaminated forms in ammonium carbonate solutions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Reactivity of Mg–Al hydrotalcites in solid and delaminated forms in ammonium carbonate solutions
چکیده انگلیسی

Treatment of Mg–Al hydrotalcites (LDHs, layered double hydroxides) in aqueous (NH4)2CO3 at 298 K leads to composites of dawsonite, hydrotalcite, and magnesium ammonium carbonate. The mechanism and kinetics of this transformation, ultimately determining the relative amounts of these components in the composite, depend on the treatment time (from 1 h to 9 days), the Mg/Al ratio in the hydrotalcite (2-4), and on the starting layered double hydroxide (solid or delaminated form). The materials at various stages of the treatment were characterized by inductive coupled plasma-optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, infrared spectroscopy, thermogravimetry, and nitrogen adsorption at 77 K. The progressive transformation of hydrotalcite towards crystalline dawsonite and magnesium ammonium carbonate phases follows a dissolution–precipitation mechanism. A gradual decrease of the Mg/Al ratio in the resulting solids was observed in time due to magnesium leaching in the reacting medium. Dawsonite–hydrotalcite composite formation is favored at high aluminum contents in the starting hydrotalcite, while the formation of magnesium ammonium carbonate is favored at high Mg/Al ratios. The synthetic strategy comprising hydrotalcite delamination in formamide prior to aqueous (NH4)2CO3 treatment is more reactive towards composite formation than starting from the bulk solid hydrotalcite.

The reactivity of LDHs in aqueous (NH4)2CO3 at 298 K has been studied over Mg–Al hydrotalcites (Mg/Al = 2-4) in solid and delaminated forms. A variety of composite mixtures of dawsonite, hydrotalcite, and magnesium ammonium carbonate are obtained.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Sciences - Volume 12, Issue 10, October 2010, Pages 1822–1830
نویسندگان
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