کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1506285 | 993788 | 2008 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Diffusion of Sr and Zr in BaTiO3 single crystals Diffusion of Sr and Zr in BaTiO3 single crystals](/preview/png/1506285.png)
The diffusion of strontium and zirconium in single crystal BaTiO3 was investigated in air at temperatures between 1000 °C and 1250 °C. Thin films of SrTiO3, deposited by spin coating a precursor solution and thin films of zirconium, deposited onto the sample surfaces by sputtering, were used as diffusion sources. The diffusion profiles were measured by SIMS depth profiling on a time-of-flight secondary ion mass spectrometer (ToF-SIMS). The diffusion coefficients of strontium and zirconium were given by DSr = 3.6 × 102.0±4.4 exp[−(543 ± 117) kJ mol−1/(RT)] cm2 s−1 and DZr = 1.1 × 101.0±2.1 exp[−(489 ± 56) kJ mol−1/(RT)] cm2 s−1. The results are discussed in terms of different diffusion mechanisms in the perovskite structure of BaTiO3.
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Journal: Solid State Sciences - Volume 10, Issue 6, June 2008, Pages 725–734