Studies on synthesis esterified zirconium glyphosates and their hydrophobic properties

A series of new organic-modified zirconium glyphosate compounds were synthesized based on the reactions between esterified glyphosates and ZrOCl2. FT-IR spectra, solid-state 31P MAS NMR and elementary analysis proved the formation of these new compounds. Powder X-ray diffraction (PXRD) patterns and transmission electron microscope (TEM) images proved these compounds had lamellar structures. Scanning electronic microscope (SEM) images showed that solvents used in synthesis had great influence on the morphologies of products. Water contact angle measurements showed that the hydrophobic property of the products was a function of the number of carbon in esterified glyphosates, increased from 0° of zirconium glyphosate to 133° of dodecyl zirconium glyphosate. The present study offered a new route to synthesize organic-modified α-Zr(HPO4)2·H2O (α-ZrP) materials with various morphology and controllable hydrophobic property.

Series of new organic-modified zirconium glyphosate compounds were synthesized. Research results proved that these compounds had lamellar structures and solvents used in synthesis had great influence on morphologies of the products. Water contact angle measurements showed that hydrophobic property of the products was a function of the number of carbon in esterified glyphosates.Figure optionsDownload as PowerPoint slide