Luminescent micro- and nanofibers based on novel europium phthalate complex

We synthesized by wet chemical route a novel europium–potassium phthalate complex Eu3+K+[(COO)2(C6H4)]2. The compound is a white powder insoluble in water. X-ray diffraction evaluation shows that we obtained a new crystalline compound with no traces of the starting materials (potassium hydrogen phthalate and europium chloride). Scanning electron microscopy reveals that the powder consists of fiber-shaped structures with sizes larger than 250 nm in diameter. Energy dispersive X-ray analysis proves that the compound has a 1:1 europium–potassium ratio. Fourier transform infrared spectroscopy confirms the presence of the phthalate in the new compound. Photoluminescence and cathodoluminescence measurements show that the fiber-shaped structures are intensely luminescent with emission bands corresponding to the 5D0 → 7FJ (J = 1–4) Eu (III) ion’s transitions in the region between 580 nm and 700 nm, the most intense maximum being observed around 615 nm. Up-converted luminescence with a maximum at 315 nm was recorded.

► A new europium–potassium phthalate complex was synthesized by wet chemical route.
► Fiber-shaped crystalline structures with sizes larger than 250 nm.
► The most probable structure of the molecule is [C6H4(COO−)2]2 K+Eu3+.
► Intense luminescence due to Eu3+ ions 5D0 → 7FJ transitions.
► Up-converted luminescence with a maximum at 315 nm was recorded.