کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1524248 995335 2012 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Luminescence and Raman study of α-Bi2O3 ceramics
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
Luminescence and Raman study of α-Bi2O3 ceramics
چکیده انگلیسی

Cathodoluminescence in the scanning electron microscope and photoluminescence in a confocal microscope have been used to investigate the luminescence properties of the stable monoclinic α-phase of Bi2O3. Powders of this oxide have been sintered at temperatures of 500 °C and 750 °C in air or in nitrogen atmospheres. Spectra of the starting powder and of the samples treated at 500 °C show luminescence bands at 1.50 eV and 1.95 eV as well as a band at 2.1 eV, more prominent in nitrogen treated samples. Sintering at 750 °C leads to quenching of the 1.50 eV infrared emission and the formation of a broad band with emission above 3 eV. The evolution of Raman bands with the sintering treatments has also been investigated.


► Influence of annealing temperature and atmosphere on the Raman spectra of α-Bi2O3.
► Cathodoluminescence (CL) spectroscopy of α-Bi2O3. Influence of annealing temperature and atmosphere.
► Assessment of α-Bi2O3 grain boundaries by spatially resolved photoluminescence.
► Correlation of CL and Raman spectra with the α-Bi2O3 defect structure.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 133, Issue 1, 15 March 2012, Pages 559–564
نویسندگان
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