کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1524627 | 995340 | 2011 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Influence of metal nanoparticle decorated CNTs on polyurethane based electro active shape memory nanocomposite actuators Influence of metal nanoparticle decorated CNTs on polyurethane based electro active shape memory nanocomposite actuators](/preview/png/1524627.png)
Polymer nanocomposites based on thermoplastic polyurethane (PU) elastomer and metal nanoparticle (Ag and Cu) decorated multiwall carbon nanotubes (M-CNTs) were prepared through melt mixing process and investigated for its mechanical, dynamic mechanical and electro active shape memory properties. Structural characterization and morphological characterization of the PU nanocomposites were done using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Morphological characterization revealed better dispersion of M-CNTs in the polyurethane, which is attributed to the improved interaction between the M-CNTs and polyurethane. Loading of the metal nanoparticle coated carbon nanotubes resulted in the significant improvement on the mechanical properties such as tensile strength of the PU composites in comparison to the pristine carbon nanotubes (P-CNTs). Dynamic mechanical analysis showed that the glass transition temperature (Tg) of the polyurethane increases slightly with increasing loading of both pristine and metal nanoparticle functionalized carbon nanotubes. The metal nanoparticles decorated carbon nanotubes also showed significant improvement in the thermal and electrical conductivity of the PU/M-CNTs nanocomposites. Shape memory studies of the PU/M-CNTs nanocomposites exhibit remarkable recoverability of its shape at lower applied dc voltages.
► Polyurethane based on pristine and metal (Ag and Cu) nanoparticle decorated CNTs nanocomposites are prepared through melt blending process.
► The electrical, mechanical, dynamic mechanical, thermal conductivity and electro active shape memory properties of the PU nanocomposites were investigated.
► The influence of metal nanoparticle decorated CNTs showed significant improvement in their all properties to compare to pristine CNTs.
► Electro active shape memory studies of the PU/M-CNTs nanocomposites reveal extraordinary recoverability of its shape at lower applied dc voltages.
Journal: Materials Chemistry and Physics - Volume 129, Issue 3, 3 October 2011, Pages 925–931