کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1525320 995354 2010 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A novel reusable platinum nanocatalyst
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
A novel reusable platinum nanocatalyst
چکیده انگلیسی

Recyclability of noble metal catalysts is a challenging issue when dealing with their industrial applications. Smart pH-sensitive Pt nanoparticles were successfully prepared for the first time by using octa(N,N-diacetic acid phenylamine)silsesquioxane (OAPAS) as a macromolecular protective agent. As-prepared Pt nanoparticles can self-aggregate or redisperse by only changing the pH of the system solution. In the weak acidic or alkaline solution (pH > 4.0), the Pt nanoparticles dispersed homogenously; while in the acidic solution (pH = 2.5), they self-aggregated. The dynamic self-aggregation and redispersion processes of the Pt nanoparticles driven by pH changes were revealed by transmission electron microscopy measurements. Electrocatalytic experiments proved that the platinum nanoparticles as a recyclable catalyst showed excellent activity for the hydrogenation of aldehyde after runs of five times. Such platinum nanoparticles are thereby anticipated to have great potential functioning as “smart” catalysts for industrial applications.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 122, Issue 1, 1 July 2010, Pages 10–14
نویسندگان
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