کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1525959 1511846 2009 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
N′-[4-(diethylamino)benzylidine]-3-{[8-(trifluoromethyl) quinolin-4-yl]thio}propano hydrazide) as an effective inhibitor of mild steel corrosion in acid media
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
N′-[4-(diethylamino)benzylidine]-3-{[8-(trifluoromethyl) quinolin-4-yl]thio}propano hydrazide) as an effective inhibitor of mild steel corrosion in acid media
چکیده انگلیسی

N′-[4-(diethylamino)benzylidine]-3-{[8-(trifluoromethyl)quinolin-4-yl]thio}propano hydrazide (DEQTPH) was newly synthesized, characterized and tested as a corrosion inhibitor for mild steel in HCl (1 M, 2 M) and H2SO4 (0.5 M, 1 M) solutions using weight loss method, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization method. The corrosion inhibition efficiencies measured by all the above three techniques were in good agreement with each other. The mild steel samples were also analyzed by scanning electron microscopy (SEM). The results showed that DEQTPH is an excellent inhibitor for mild steel in acid media. The inhibition efficiency in different acid media was found to be in the order, 0.5 M H2SO4 > 1.0 M HCl > 2.0 M HCl > 1.0 M H2SO4. The inhibition was assumed to occur via adsorption of the inhibitor molecule on the metal surface. It acts as an anodic inhibitor. In the 30–60 °C temperature range, the DEQTPH adsorption follows Langmuir isotherm model. The protection efficiency increased with increasing inhibitor concentration in the range 0.2 × 10−4 to 10.5 × 10−4 M and slightly increased with increasing temperature. Thermodynamic characteristics were discussed. Chemisorption mechanism is proposed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 115, Issues 2–3, 15 June 2009, Pages 618–627
نویسندگان
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