Formulation and screen printing of water based conductive flake silver pastes onto green ceramic tapes for electronic applications

Environmentally friendly, water-based silver pastes, adapted for screen printing, were formulated with different silver contents (67–75%). These pastes allowed screen printing onto low temperature co-fired ceramic (LTCC) of narrow conductive tracks with a 60 μm line width and a 3 × 10−8 Ω m electrical resistivity. Inks were formulated with a mixture of spherical and flake shape silver particles with 2–4 μm mean diameter. Rheological behaviour of pastes was studied in order to determine its effect on printed lines properties. Prepared inks were then screen printed and sintered under normal atmosphere at 875 °C. As expected, electrical properties depended on silver content. Resistivity values varying from 1.6 × 10−8 to 3.3 × 10−8 Ω m were calculated over 36.3 cm line length. These values are very close to bulk silver resistivity (1.6 × 10−8 Ω m). Compared to previous research and commercial pastes, the newly formulated pastes reached equivalent or even better conductivities with lower silver content (70% by weight).

► Formulation of water-based pastes.
► Viscosity, yield stress, elastic and viscous modulus determination.
► Screen printing onto green ceramic tapes.
► Rheology effect on line dimensions and electrical properties.
► Resistivity ∼18–33 nΩ m. Minimum width ∼60 μm after sintering.