Corrosion and impedance studies on magnesium alloy in oxalate solution

Corrosion behavior of AZ91E alloy was investigated in oxalate solution using potentiodynamic polarization and electrochemical impedance measurements (EIS). The effect of oxalate concentration was studied, where the corrosion rate increases with increasing oxalate concentration. The effect of added ions (Br−, Cl− or SiO32−) on the electrochemical behavior of magnesium alloy in 0.1 M Na2C2O4 solution at 298 K, was investigated. It was found that the corrosion rate of 0.1 M oxalate solution containing silicate ion is lower than the blank (0.1 M Na2C2O4). This was confirmed by scanning electron microscope (SEM) observations. However, for the other added ions Br− or Cl−, the corrosion rate is higher than the blank.

► Corrosion behavior of AZ91E alloy was investigated in 0.1 M Na2C2O4 containing different additives as Br−, Cl− or Silicate.
► The corrosion rate of 0.1 M oxalate solution containing silicate ion is lower than the blank (0.1 M Na2C2O4). This was confirmed by scanning electron microscope (SEM) observations.
► For the other added ions Br− or Cl−, the corrosion rate is higher than the blank.