Nonlinear optical properties and photoinduced anisotropy of an azobenzene ionic liquid–crystalline polymer

The nonlinear optical properties and photoinduced anisotropy of an azobenzene ionic liquid–crystalline polymer were investigated. The single beam Z-scan measurement showed the polymer film possessed a value of nonlinear refractive index n2 = −1.07 × 10−9 cm2/W under a picosecond 532 nm excitation. Photoinduced anisotropy in the polymer was studied through dichroism and photoinduced birefringence. A photoinduced birefringence value Δn ∼ 10−2 was achieved in the polymer film. The mechanism for the nonlinear optical response and the physical process of photoinduced anisotropy in the polymer were discussed.