Refinement of the thermodynamic modeling of the Nb–Ni system

The Nb–Ni system is reassessed on the basis of a critical literature review involving recent experimental data. These newly published experimental data include the phase relation associated with the NbNi8 phase, phase transition temperatures resulting from selected alloys, all invariant reaction temperatures, and enthalpies of mixing of liquid, as well as the crystallographic data on the μμ (Nb7Ni6) phase. A consistent thermodynamic data set for the Nb–Ni system is obtained by optimization of the selected experimental values. The calculated phase diagram, crystallographic properties and thermodynamic properties agree reasonably with the experimental data. Noticeable improvements have been made, compared with the previous thermodynamic optimizations.