Comparative study of optical and structural properties of electrospun 1-dimensional CaYAl3O7:Eu3 + nanofibers and bulk phosphor

• Synthesis of red nano-phosphor through electrospinning
• Luminescence properties of bulk and nano-phosphors are compared.
• Inferior emission intensity of the nano-phosphor is analyzed using MEM.
• Charge cloud around nano-phosphor was found to be oblique.

We report the optical and structural studies of Eu3 +-doped 1-dimensional CaYAl3O7 nano-fiber phosphor. CaYAl3O7:Eu3 + phosphors were synthesized by electrospinning technique and the pristine nano-fibers were annealed at 900 °C to form well crystallized uniform fibers. Under ultraviolet excitation, the CaYAl3O7:Eu3 + exhibited red emission, due to transitions in the 4f states of Eu3 +. In order to explore the difference between the quantum efficiency of nano-fiber and bulk CaYAl3O7:Eu3 + phosphor, detailed structural and optical analyses were carried out. The structural analysis of the CaYAl3O7:Eu3 + nano-fibers indicates that the structural environment surrounding the dopant Eu3 + ion was more unstable in nano-fiber when compared to a bulk sample. Decay curves for both the samples when fitted with double exponential decay model indicate that the nano-fiber has shorter decay time, arising from the larger contribution from the non-radiative decay, due to defect levels introduced in the host lattice.