Fabrication and characterization of magnesium–fluorapatite nanocomposite for biomedical applications

Recent studies indicate that there is a high demand for magnesium alloys with adjustable corrosion rates, suitable mechanical properties, and the ability for precipitation of a bone-like apatite layer on the surface of magnesium alloys in the body. An approach to this challenge might be the application of metal matrix composites based on magnesium alloys. The aim of this work was to fabricate and characterize a nanocomposite made of AZ91 magnesium alloy as the matrix and fluorapatite nano particles as reinforcement. A magnesium–fluorapatite nanocomposite was made via a blending–pressing–sintering method. Mechanical, metallurgical and in vitro corrosion measurements were performed for characterization of both the initial materials and the composite structure. The results showed that the addition of fluorapatite nano particle reinforcements to magnesium alloys can improve the mechanical properties, reduce the corrosion rate, and accelerate the formation of an apatite layer on the surface, which provides improved protection for the AZ91 matrix. It is suggested that the formation of an apatite layer on the surface of magnesium alloys can contribute to the improved osteoconductivity of magnesium alloys for biomedical applications.

(a), (b) SEM photomicrographs of AZ91-20FA sample in two magnifications and (c) TEM photomicrograph of AZ91-20FA sample.Figure optionsDownload as PowerPoint slideResearch Highlights
► A magnesium based nanocomposite was made via a blending–pressing–sintering method.
► FA nano particle reinforcements improve the mechanical properties.
► FA nano particle reinforcements reduce the corrosion rate.
► FA nano particle reinforcements accelerate the formation of an apatite layer.
► The apatite layer on the surface provides improved protection for the AZ91 matrix.