کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1578912 | 1001216 | 2011 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Microstructure investigation and first-principle analysis of die-cast AZ91 alloy with calcium addition Microstructure investigation and first-principle analysis of die-cast AZ91 alloy with calcium addition](/preview/png/1578912.png)
In order to get improved mechanical properties of die-cast AZ91 alloy under elevated temperatures, Ca element was added as a cost-effective alloying constituent. It appeared that minor Ca addition less than 0.5 wt% would result in no apparent change in microstructure, but the tensile strength at elevated temperatures was improved considerably. When increasing Ca addition to more than 1.0 wt%, Al2Ca phase will precipitate during solidification, no Mg2Ca phase was discovered. Homogeneous microstructure and high temperature stability in tensile strength of die-cast AZ91 alloy with Ca addition was mainly attributed to the precipitation of Al2Ca phase, which considerably refined the bulky β-Mg17Al12 phase distributed originally at the grain boundaries of die-cast AZ91 alloy with no Ca addition. The priority of Al2Ca phase compared to Mg2Ca phase in precipitation sequence was verified by first-principle calculation of their cohesive energy and formation enthalpy, and can also be associated with more bounding electrons between Al and Ca atoms.
► Die-cast AZ91 with Ca addition was investigated experimentally and theoretically.
► Precipitation sequence was confirmed with increasing Ca addition.
► Phase stability difference was verified by first-principle calculation.
► Valence configurations were associated with alloying effects of Al, Mg and Ca.
Journal: Materials Science and Engineering: A - Volume 528, Issue 15, 15 June 2011, Pages 5283–5288