کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1586108 1514929 2006 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Relation between the oxidation mechanism of nickel, the microstructure and mechanical resistance of NiO films and the nickel purity: I. Oxidation mechanism and microstructure of NiO films
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
Relation between the oxidation mechanism of nickel, the microstructure and mechanical resistance of NiO films and the nickel purity: I. Oxidation mechanism and microstructure of NiO films
چکیده انگلیسی

The effect of impurities on the oxidation mechanism of nickel and on the mechanical characteristics of NiO films was studied on two industrial nickel grades compared to a pure nickel. In this part, influence of impurities on the oxidation mechanism and on the NiO film microstructure will be detailed. The oxidation mechanism, especially studied at 800 °C in air, was clarified using complementary techniques, SEM and STEM microstructural and analytical investigations, XPS analyses, profilometry, oxygen isotopic exchange and SIMS. Depending on the Ni purity, the morphology of the oxide scale and the porosity amount differs. Duplex oxide layers and internal oxidation are observed on industrial grades, while a simple NiO film grows on pure nickel without internal oxidation. An oxidation mechanism, which differs according to the presence or not of impurities in the nickel substrate, is proposed. The mechanical characteristics will be characterised and discussed in the following paper (part II) in relation with the microstructural modifications induced by changing the nickel purity.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Science and Engineering: A - Volume 415, Issues 1–2, 15 January 2006, Pages 21–32
نویسندگان
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