کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1588670 | 1515127 | 2016 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Microstructural investigations of carbon foams derived from modified coal-tar pitch
ترجمه فارسی عنوان
تحقیقات میکرو سازنده فومهای کربن حاصل از زمین اصلاح شده ذغال سنگ
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
دانش مواد (عمومی)
چکیده انگلیسی
This work reports the microstructural evaluation of carbon foams derived from coal-tar pitch precursors treated with H2SO4 and HNO3 and finally annealed at 1000 °C and 2000 °C. Our experimental investigations combine scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM) imaging, X-ray photoelectron spectroscopy (XPS) and micro-spot near-edge X-ray absorption fine structure (μ-NEXAFS) spectroscopy. This set of complementary techniques provides detailed structural and chemical information of the surface and the bulk of the carbon foams. The high-resolution microscopy data indicate the formation of carbonaceous amorphous microspheres (average diameters of 0.28 ± 0.01 μm) embedded in the partially graphitized carbon foam matrix at 1000 °C. The microspheres are enriched with sp-bonded species and their microstructural characteristics depend on the reagent (nitric vs. sulfuric acid) used for pitch treatment. A complete chemical transformation of the microspheres at temperaturesâ>1000 °C occurs and at 2000 °C they are spectroscopically identical with the bulk material (sp2- and sp3-hybridised forms of carbon). The microstructure-property relationship is exemplified by the compressive strength measurements. These results allow a better description of coal-tar pitch-derived carbon foams at the atomic level, and may account for a better understanding of the processes during graphitization step.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Micron - Volume 89, October 2016, Pages 34-42
Journal: Micron - Volume 89, October 2016, Pages 34-42
نویسندگان
George Tzvetkov, Boyko Tsyntsarski, Konstantin Balashev, Tony Spassov,