کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1591056 | 1515557 | 2016 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Crystal structure and high-temperature properties of (Pr,Sr)2(Co,Mn)O4±δ with K2NiF4-type structure
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Novel oxides PrSrCo1âyMnyO4±δ, 0.0â¤yâ¤0.5 and Pr0.5Sr1.5Co1âyMnyO4±δ 0.3â¤yâ¤0.5 with K2NiF4-type structure were synthesized. The crystal structure, oxygen content, thermal expansion and electrical conductivity of the obtained compounds were examined. A chemical titration showed that PrSrCo0.5Mn0.5O4±δ is slightly overstoichiometric (δ=0.03(2)), while Pr0.5Sr1.5Co0.5Mn0.5O4±δ is oxygen deficient (δ=â0.05(2)). Thermal expansion behavior was studied by both dilatometry and high-temperature X-ray powder diffraction in the temperature range of 298-1173 K in air. Pr0.5Sr1.5Co0.5Mn0.5O3.95(2) exhibited linear thermal expansion along the a- and c-axes over the studied temperature range with thermal expansion coefficients (TECs) were 17.5 ppm Kâ1 and 17.8 ppm Kâ1, respectively. For PrSrCo0.5Mn0.5O4.03(2) two regions (298-600 K and 600-1173 K) observed, where the TEC along the a-axis decreased from 12.7 ppm Kâ1 to 10.4 ppm Kâ1 whereas the TEC along the c-axis increased from 14.5 ppm Kâ1 to 26.7 ppm Kâ1. Both compounds demonstrated lower in comparison with undoped PrSrCoO4 values of electrical conductivity of 7 S/cm for PrSrCo0.5Mn0.5O4.03(2) and 23 S/cm for Pr0.5Sr1.5Co0.5Mn0.5O3.95(2) at 1173 K in air.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Communications - Volume 245, November 2016, Pages 31-35
Journal: Solid State Communications - Volume 245, November 2016, Pages 31-35
نویسندگان
E.V. Zharikova, M.G. Rozova, S.M. Kazakov, S.Ya. Istomin, N.V. Lyskov, E.V. Antipov,