کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1637759 | 1516985 | 2013 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Kinetics of cobalt(II) extraction from sulfate aqueous solution by sodium salt of di-decylphosphinic acid (DDPA)
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Kinetics of Co(II) extraction from sulfate aqueous solution by the sodium salt of di-decylphosphinic acid (Na-DDPA) was studied using a modified Lewis cell to disclose the mechanism of extraction. Parameters affecting the extraction rate, such as stirring speed, temperature, interfacial area, Na-DDPA concentration and Co(II) concentration, were investigated, respectively. The effect of diffusion resistance on extraction rate was negligible when the stirring operation was conducted in a plateau region of 95-110 r/min. Extraction rate increased with the increase in the temperature or specific interfacial area. The activation energy E was calculated to be 32.75 kJ/mol. These suggested that rate controlling mechanism of Co(II) extraction by Na-DDPA was chemical reaction regime and the rate-determining step of Co(II) extraction was chemical reaction at the interface. The initial extraction rate also increased with the increase in the concentrations of Na-DDPA and Co(II). The extraction rate equation and mechanism of Co(II) extraction by Na-DDPA were proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Transactions of Nonferrous Metals Society of China - Volume 23, Issue 2, February 2013, Pages 517-523
Journal: Transactions of Nonferrous Metals Society of China - Volume 23, Issue 2, February 2013, Pages 517-523
نویسندگان
Peng XING, Cheng-yan WANG, Sheng-ming XU, Zhong-jun JU,