کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1641913 1517224 2016 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
High-contrast reversible mechanochromic luminescence of a conjugated anthracene-based molecule
ترجمه فارسی عنوان
لومینسانسی مکانیکرومیک برگشت پذیر به صورت کنسانتره مولکول مبتنی بر آنتراسن کانژوگه
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
چکیده انگلیسی


• A anthracene-based compound with large steric effect was synthesized.
• The title compound BDPIA emits strong fluorescence in the solid state.
• BDPIA exhibits mechanochromic property with high-contrast.
• The mechanochromism of BDPIA is ascribed to the regulation of intermolecular π–π stacking.

We report a solid-emissive anthracene-based compound with rigid conjugated structure, which exhibits strong blue fluorescence in the crystalline state. Grinding the crystals turns its initial blue emission to green with higher emission efficiency, and the blue emission could be recovered by fume with isobutanol. The phenomenon was suggested to be due to the regulation of π–π stacking between the aromatic rings by mechanical and fume stimuli.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 164, 1 February 2016, Pages 239–242
نویسندگان
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