کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1642296 1517229 2015 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrophoretic stabilization of freestanding pristine graphene foams with carbon nanotubes for enhanced optical and electrical response
ترجمه فارسی عنوان
تثبیت الکتروفورز از فوم های گرافیتی مجزا با نانولوله های کربنی برای افزایش پاسخ نوری و الکتریکی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
چکیده انگلیسی


• A freestanding 3D graphene foam material can be prepared without polymer stabilization.
• Pristine SWCNT coatings are applied to 3D foams through electrophoretic deposition.
• Conventional polymer stabilization of graphene leaves residue that compromises properties.
• SWCNT vs. PMMA stabilization of 3D graphene leads to 50x improved electrical conductivity.
• SWCNT vs. PMMA stabilization of 3D graphene leads to 10 cm−1 redshift in Raman 2D mode.

Graphene materials, including three-dimensional foams, are commonly transferred from growth substrates using polymer stabilization processes. Even after harsh chemical and annealing treatments to remove the polymer, residues remain which compromise the electronic, thermal, gravimetric, and chemical properties of the graphene. To overcome this, we present a scalable, clean approach to stabilize graphene foams by conformal electrophoretic deposition of web-like networks of surfactant-free single-walled carbon nanotubes directly from polar solvents. We demonstrate these coatings to yield a pristine stabilized graphene material exhibiting 50x lower electrical resistance and a 10 cm−1 optical red-shift in the Raman G′ double resonance mode in comparison to polymer-stabilized graphene. This approach enables the formation of three-dimensional architectures of nanomaterials without the adverse effects associated with residual impurities from polymer and chemical processing.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 159, 15 November 2015, Pages 261–264
نویسندگان
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