کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1644728 | 1517272 | 2014 | 4 صفحه PDF | دانلود رایگان |
• New crystalline/amorphous composite was synthesized by the rapidly melt-spun process.
• Phase separation and amorphous formation in Cu–Ni-Nb ribbon were investigated.
• The formation mechanism of the composite with droplet-type microstructure was analyzed.
Liquid phase separation phenomena give rise to a unique opportunity in developing the crystalline/amorphous composites using melt-spinning method. In this study, a new crystalline/amorphous composite with a droplet-type microstructure is investigated in Cu–Ni–Nb immiscible system. It is found that the Cu30(Ni38Nb62)70 alloy undergoes liquid–liquid phase separation in the undercooled liquid state, and then solidifies into Cu-rich crystalline phase and NiNb-based amorphous phase. The fcc Cu-rich crystalline droplets are dispersed in the NiNb-based amorphous matrix. The grain size of Cu-rich droplets is in the range between nanometer dimension order and micrometer order. On the other hand, an obvious layer without Cu-rich nanoparticles is observed near the wheel side. The indentation testing of Cu30(Ni38Nb62)70 ribbon shows a larger elastic–plastic deformation area and much smaller Vickers hardness, due to the formation of softer Cu-rich particles. Further results indicate that the formation of droplet-type microstructure could be attributed to the liquid phase separation and amorphous phase formation.
Journal: Materials Letters - Volume 116, 1 February 2014, Pages 328–331