کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1648251 | 1007553 | 2011 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Layered δ-MnO2 as positive electrode for lithium intercalation Layered δ-MnO2 as positive electrode for lithium intercalation](/preview/png/1648251.png)
Layer structured δ-MnO2 was synthesized by a microwave-assisted hydrothermal method. The morphology of the product consists of flower-like spheres that range from about 200 nm to 3 μm in diameter and are composed of sheets about 5–10 nm in thickness. When tested in the voltage range of 2 to 4.5 V vs. Li+/Li in coin cells, the separator is blocked, handicapping Li+ conductivity and leading to cell failure. When tested in the voltage range of 2 to 4 V in ethylene carbonate/dimethyl carbonate (EC/DMC), the δ-MnO2 delivers an initial reversible capacity of 143.7 mAh g−1 and can maintain 120 mAh g−1 at the 60th cycle. The δ-MnO2 electrode shows good cycling stability at different current densities and delivers a discharge capacity of about 90 mAh g−1 at 1 C, indicating that it is a promising cathode material for lithium ion batteries.
Journal: Materials Letters - Volume 65, Issue 9, 15 May 2011, Pages 1319–1322