کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1648617 | 1007561 | 2010 | 4 صفحه PDF | دانلود رایگان |
A new Pb(II) one-dimensional coordination polymer, [Pb(µ-NO2)(µ-pyc)(H2O)]n (1), Hpyc = 2-pyridinecarboxylic acid} was prepared and characterized by elemental analyses, powder XRD diffraction and IR spectroscopy. Compound 1 was structurally characterized by single-crystal X-ray diffraction and one-dimensional coordination polymer with coordination environment of PbNO6. The thermal stability of compound 1 showed that compound 1 decomposes at 110–500 °C and the final product is PbO. This polymeric precursor has been used to make PbO nano-particles using two different surfactants. The new nano-structure was characterized by scanning electron microscopy and X-ray powder diffraction. This study demonstrates that the coordination polymers may be suitable precursors for the preparation of nanoscale materials.
Journal: Materials Letters - Volume 64, Issue 7, 15 April 2010, Pages 810–813