کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1652025 | 1007635 | 2007 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermal, photophysical, and electrochemical characterization of a conjugated polyazomethine prepared by anodic electropolymerization of a thiophenoazomethine co-monomer
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Thermal, photophysical, and electrochemical characterization of a conjugated polyazomethine prepared by anodic electropolymerization of a thiophenoazomethine co-monomer Thermal, photophysical, and electrochemical characterization of a conjugated polyazomethine prepared by anodic electropolymerization of a thiophenoazomethine co-monomer](/preview/png/1652025.png)
چکیده انگلیسی
A novel conjugated azomethine co-monomer consisting uniquely of thiophenes is presented, which was prepared by a simple condensation reaction in the absence of solvent. The conjugated thiophenoazomethine triad sustained anodic electropolymerization to afford a conjugated polymer that was deposited as a thin film onto a transparent ITO electrode. The resulting polymer undergoes unprecedented reversible radical cation formation in addition to a reduction, illustrating its p- and n-type character. The measured spectroscopic properties showed that the polymer is conjugated with a low band-gap ca. 1.5 eV and its excited state energy is dissipated by nonradiative means.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 61, Issue 29, December 2007, Pages 5102–5106
Journal: Materials Letters - Volume 61, Issue 29, December 2007, Pages 5102–5106
نویسندگان
Sergio Andrés Pérez Guarìn, W.G. Skene,