کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1652573 1517337 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation and characterization of host (mesoporous aluminosilicate material)–guest (semiconductor nanoparticles) nanocomposite materials
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Preparation and characterization of host (mesoporous aluminosilicate material)–guest (semiconductor nanoparticles) nanocomposite materials
چکیده انگلیسی

We report the optical and structural properties of NiS and CoS nanoparticles in AlMCM-41 zeolite. The samples were obtained by sulfidation of the Ni2+ and Co2+ ion exchange zeolite in a Na2S solution at room temperature. The optical properties of the samples were studied by UV–Vis spectroscopy. Their crystalline structure and morphology were studied by XRD and scanning electron microscopy (SEM). The results show that the nanoparticles grow outside the mesopore AlMCM-41 matrix. Exciton absorption peaks at higher energy than the fundamental absorption edge of bulk NiS and CoS indicate quantum confinement effects in nanoparticles as a consequence of their small size. The absorption spectra show that the optical band gap varies in the range 3.53–4.47 eV.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 62, Issues 4–5, 29 February 2008, Pages 655–658
نویسندگان
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