Room temperature co-precipitation of nanocrystalline CeO2 and Ce0.8Gd0.2O1.9−δ powder

This paper describes a simple method to co-precipitate CeO2 and Ce0.8Gd0.2O1.9−δ with ammonium hydroxide from solvents such as: water, ethylene glycol, ethyl alcohol and isopropyl alcohol. Characterization by Raman spectroscopy and XRD evidenced the formation of a solid solution of gadolinium-doped ceria at room temperature. Nanometric particles with crystallite size of 3.1 nm were obtained during synthesis using ethyl alcohol as solvent. This is a promising result compared with those mentioned in the literature, in which the smallest crystallite size reported was 6.5 nm.