کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1652986 1007653 2007 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Tuning the Eu luminescence in glass materials synthesized in air by adjusting glass compositions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Tuning the Eu luminescence in glass materials synthesized in air by adjusting glass compositions
چکیده انگلیسی

The doped Eu3+ ions can be partly reduced to Eu2+ in a series of MO–B2O3: Eu (M = Ba, Sr, Ca) glasses synthesized in air atmosphere, but not in the 12CaO–7Al2O3: Eu glass. The different redox-behavior of Eu ions in these two glass systems is attributed to the different host optical basicity. It is found that a lower valence state of Eu2+ is more favorable in acidic glasses, which have lower optical basicities. A notion of the critical value of optical basicity is introduced empirically, which can be used as a guide for the selection of glass composition suitable to incorporate Eu2+ for luminescence.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 61, Issue 17, July 2007, Pages 3608–3611
نویسندگان
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