کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1654083 | 1517348 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of polypyrrole and carbon nano-fiber composite for the electrode of electrochemical capacitors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis of polypyrrole and carbon nano-fiber composite for the electrode of electrochemical capacitors Synthesis of polypyrrole and carbon nano-fiber composite for the electrode of electrochemical capacitors](/preview/png/1654083.png)
چکیده انگلیسی
Nano-thin polypyrrole (PPy) films were deposited on vapor grown carbon fibers (VGCF) by using an in situ chemical polymerization of the monomer in the presence of FeCl3 oxidant. An ultrasonic cavitational stream was used during polymerization of pyrrole, to enable the deposition of uniformly nano-thin PPy films on the surface of VGCF. The PPy/VGCF composite was characterized by FTIR spectroscopy. Surface morphology of the polymer films was characterized by using scanning electron microscopy and scanning transmission electron microscopy. The capacitance of the composite electrodes was investigated with cyclic voltammetry. As results of this study, thinner layer of PPy in the composite electrode (< 10 nm) was effective to obtain fully reversible and very fast Faradaic reaction. Hence, most mass of the PPy could contribute to the pseudo-capacitive charge storage. This nano-thin PPy layer exhibited higher specific capacitance of â¼588 F gâ 1 at 30 mV sâ 1 and â¼545 F gâ 1 at 200 mV sâ 1 along with an excellent power capability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 60, Issues 13â14, June 2006, Pages 1697-1701
Journal: Materials Letters - Volume 60, Issues 13â14, June 2006, Pages 1697-1701
نویسندگان
Jong-Huy Kim, Ashok K. Sharma, Yong-Sung Lee,