کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1657229 1517613 2015 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Oxidation behavior of pack-cemented Si–B oxidation protection coatings for Mo–Si–B alloys at 1300 °C
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Oxidation behavior of pack-cemented Si–B oxidation protection coatings for Mo–Si–B alloys at 1300 °C
چکیده انگلیسی


• The improvement in mass change comparing coated and uncoated samples is remarkable.
• The mass change was decreased by 99.8% comparing coated and uncoated materials.
• This shows the potential of coated Mo–9Si–8B for application at high temperatures.
• The interdiffusion growth of the multilayer structure shows a preferential behavior.

To enhance the resistance to oxidation and prolong the lifetime, oxidation protection coatings were applied on Mo–9Si–8B (in at.%) alloy substrates by Si–B co-pack cementation. Subsequently, the samples were conditioned at 1450 °C for 8 h in air to develop an outer 10 μm thick aluminoborosilicate scale. A multilayered microstructure of MoSi2, Mo5Si3, and Mo5SiB2/MoB of about 80 μm thick was observed underneath the scale. During cyclic testing between room temperature and 1300 °C the samples exhibited a very low mass change of only up to +/− 0.2 mg/cm2 within 500 h at high temperature. During oxidation the MoSi2 phase layer was partially consumed by silica and Mo5Si3 formation. No high material regression due to MoO3-evaporation took place during testing. However, a low mass loss during the first 100 h of testing was observed, presumably due to stress cracking caused by thermal mismatch of coating and substrate accompanied by subsequent healing. The stresses were reduced by the growth texture in the [001] direction of the Mo5Si3-phase. In comparison to the uncoated substrate material, the mass change was decreased by 99.8%. This points to a significantly prolonged lifetime and shows the huge potential of coated Mo–9Si–8B alloys for application at very high temperatures and under thermal cycling loads.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Surface and Coatings Technology - Volume 266, 25 March 2015, Pages 57–63
نویسندگان
, , , ,