کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1659288 | 1008375 | 2011 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Low temperature growth of nanocrystalline TiO2 films with Ar/O2 low-field helicon plasma Low temperature growth of nanocrystalline TiO2 films with Ar/O2 low-field helicon plasma](/preview/png/1659288.png)
TiO2 thin films were deposited on silicon wafer substrates by low-field (1 < B < 5 mT) helicon plasma assisted reactive sputtering in a mixture of pure argon and oxygen. The influence of the positive ion density on the substrate and the post-annealing treatment on the films density, refractive index, chemical composition and crystalline structure was analysed by reflectometry, Rutherford backscattering spectroscopy (RBS) and X-ray diffraction (XRD). Amorphous TiO2 was obtained for ion density on the substrate below 7 × 1016 m− 3. Increasing the ion density over 7 × 1016 m− 3 led to the formation of nanocrystalline (~ 15 nm) rutile phase TiO2. The post-annealing treatment of the films in air at 300 °C induced the complete crystallisation of the amorphous films to nanocrystals of anatase (~ 40 nm) while the rutile films shows no significant change meaning that they were already fully crystallised by the plasma process. All these results show an efficient process by low-field helicon plasma sputtering process to fabricate stoichiometric TiO2 thin films with amorphous or nanocrystalline rutile structure directly from low temperature plasma processing conditions and nanocrystalline anatase structure with a moderate annealing treatment.
Research highlights
► Low magnetic field helicon mode for plasma material processing.
► Low temperature growth of nanocrystalline titanium dioxide.
► Effect of the positive ions flux on the formation of crystalline titanium dioxide.
Journal: Surface and Coatings Technology - Volume 205, Issue 15, 25 April 2011, Pages 3939–3946