کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1685909 | 1010580 | 2011 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Oxygen deficiency and excess of rutile titania (1Â 1Â 0) surfaces analyzed by ion scattering coupled with elastic recoil detection
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سطوح، پوششها و فیلمها
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Oxygen deficiency and excess of rutile titania (1Â 1Â 0) surfaces analyzed by ion scattering coupled with elastic recoil detection Oxygen deficiency and excess of rutile titania (1Â 1Â 0) surfaces analyzed by ion scattering coupled with elastic recoil detection](/preview/png/1685909.png)
چکیده انگلیسی
Oxygen deficiency and excess of rutile titania (TiO2) surfaces are important factors for catalytic activities of metal nano-particles on the TiO2 supports. Medium energy ion scattering (MEIS; 80 keV He+) coupled with elastic recoil detection analysis (ERD; 150 keV Ne+) can determine the numbers of bridging O (Obr) vacancies (VO) and excess O atoms adsorbed on the 5-fold Ti rows of TiO2(1 1 0) surfaces. The amounts of VO and adsorbed O were derived by H2O and 18O2 exposure followed by ERD and MEIS analyses, respectively. The present analysis revealed that only about a half of VO are filled and a comparable amount of O atoms are adsorbed on the reduced TiO2(1 1 0) surface after exposure to O2 (1000 L; 1 L = 1 Ã 10â6 Torr s) at room temperature (RT). We also detected the adsorbed O for the hydroxylated TiO2(1 1 0) after 18O2 exposure at RT. Finally, it is shown that the O adsorbed on the Ti rows reacts with CO probably to form CO2 at RT. Based on the results obtained here, we clarify the reason why only a half of VO are filled by exposing reduced surface to O2 at RT and what is the primary source of subsurface excess electronic charge, which acts as a leading part of the surface electrochemistry and gives the defect state in the band gap seen in the valence band spectra for reduced and hydroxylated TiO2(1 1 0) surfaces.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms - Volume 269, Issue 16, 15 August 2011, Pages 1859-1864
Journal: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms - Volume 269, Issue 16, 15 August 2011, Pages 1859-1864
نویسندگان
Kei Mitsuhara, Taishi Matsuda, Hideki Okumura, Anton Visikovskiy, Yoshiaki Kido,