کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1694024 1519057 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effects of imperfect interfacial adhesion between polymer and nanoparticles on the tensile modulus of clay/polymer nanocomposites
ترجمه فارسی عنوان
اثر چسبندگی بین فضای نازک بین پلیمر و نانوذرات بر روی مدول کششی نانو کامپوزیتهای رس / پلیمر
کلمات کلیدی
نانوکامپوزیت های خاک رس / پلیمر؛ مدول کششی؛ چسبندگی ناحیه نامناسب؛ مدلهای هالپین تسای و هوی شیعا
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات ژئوشیمی و پترولوژی
چکیده انگلیسی


• The models for a perfect interface overpredict the tensile modulus in nanocomposites.
• The effects of incomplete interfacial adhesion on the tensile modulus are studied.
• The models apply the defined effective aspect ratio and volume fraction of nanoclay.
• The values and roles of “Lc” and “τ” on the tensile modulus are evaluated.
• Low “Lc” and high “τ” result in a significant modulus in nanocomposites.

This work investigates the effects of incomplete interfacial adhesion between polymer and nanoparticles on the predicted tensile modulus of clay/polymer nanocomposites (CPNs). The Halpin-Tsai and Hui-Shia models which assume the perfect interfacial adhesion commonly overpredict the modulus in CPN. Accordingly, the samples include imperfect interfacial bonding at polymer-filler interface. In this condition, the effective aspect ratio and volume fraction of nanoclay are defined using “Lc” as the essential distance for the normal stress to reach the clay strength and “τ” as the interfacial shear strength. The values of “Lc” and “τ” are calculated for several samples and also, their roles in the predicted modulus are determined. It is shown that low “Lc” and high “τ” result in a significant modulus, because they indicate the great levels of interfacial properties in CPN. Also, the large and thin platelets can produce a high modulus depending to the level of Interfacial parameters.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Clay Science - Volume 129, August 2016, Pages 65–70
نویسندگان
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